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    • 1. 发明申请
    • CURABLE RESIN COMPOSITION
    • 可固化树脂组合物
    • US20130018168A1
    • 2013-01-17
    • US13580803
    • 2011-02-08
    • Hitoshi OkazakiMotoharu Takeuchi
    • Hitoshi OkazakiMotoharu Takeuchi
    • C08G75/14
    • C08G75/08C08L81/02
    • The invention relates to a curable composition preferable as a raw material for optical materials such as adhesive agents for optical elements, coating agents for optical elements, resist materials, prisms, optical fibers, information recording substrates, filters and plastic lenses, and more specifically to a curable composition characterized by containing (A) an episulfide compound, and (B) a polymerization catalyst comprising a tetraalkylphosphonium dialkylphosphate represented by the following general formula (1): wherein R1 to R6 are the same or different, an alkyl group having 1 to 8 carbon atoms or an alkyl group having a hydroxyl group and 1 to 8 carbon atoms, and linear, branched or cycloaliphatic.
    • 本发明涉及一种优选作为光学材料的原料的光固化性组合物,例如光学元件用粘合剂,光学元件用涂布剂,抗蚀剂材料,棱镜,光纤,信息记录基材,过滤器和塑料透镜,更特别地涉及 一种固化性组合物,其特征在于含有(A)环硫化合物,和(B)包含由以下通式(1)表示的磷酸二烷基鏻四烷基鏻的聚合催化剂:其中R 1至R 6相同或不同, 8个碳原子或具有羟基和1至8个碳原子的烷基,以及直链,支链或脂环族。
    • 4. 发明申请
    • CURABLE COMPOSITION
    • 可固化组合物
    • US20160152774A1
    • 2016-06-02
    • US14899509
    • 2014-06-26
    • MITSUBISHI GAS CHEMICAL COMPANY, INC.
    • Kousuke NamikiHitoshi OkazakiEiji KoshiishiSawako FuseKikuo Furukawa
    • C08G75/08C09J181/02
    • C08G75/08C09J181/02
    • According to the present invention, a curable composition can be provided, said composition being characterized by comprising: (A) an episulfide compound; and (B) a photobase generator comprising an organoboron compound represented by general formula (1) below: (In general formula (1), R1, R2, R3, R4 and R5 may be the same as or different from one another and independently represent an alkyl group having 1 to 8 carbon atoms; and Ar1, Ar2 and Ar3 may be the same as or different from one another and independently represent a group selected from the group consisting of a phenyl group, a naphthyl group, an anthracenyl group and a phenanthryl group, each of which may have a substituent selected from the group consisting of an alkyl group, an aryl group, an alkenyl group, a cycloalkyl group and a heterocyclic group.)
    • 根据本发明,可以提供可固化组合物,所述组合物的特征在于包含:(A)环硫化合物; 和(B)含有下述通式(1)表示的有机硼化合物的光碱产生剂:(通式(1)中,R 1,R 2,R 3,R 4和R 5可以相同也可以不同, 具有1至8个碳原子的烷基; Ar 1,Ar 2和Ar 3可以彼此相同或不同,并且独立地表示选自苯基,萘基,蒽基和 菲基,其各自可以具有选自烷基,芳基,烯基,环烷基和杂环基的取代基。)
    • 9. 发明授权
    • Photocurable composition and coating composition
    • 可光固化组合物和涂料组合物
    • US07691555B2
    • 2010-04-06
    • US10563868
    • 2004-08-04
    • Hitoshi OkazakiJunya HayakawaMotoharu TakeuchiMasahiro JohnoKenji Ishii
    • Hitoshi OkazakiJunya HayakawaMotoharu TakeuchiMasahiro JohnoKenji Ishii
    • G03F7/004G03F7/028
    • C09D181/02C08G75/08C08K5/45Y10S430/121
    • There are provided a photocurable composition capable of being readily cured by irradiation of ultraviolet rays and a cured product of the photocurable composition, as well as a coating composition and a coating film obtained from the coating composition. The cured product exhibits a high refractive index, a less discoloration and an excellent transparency. The present invention relates to a photocurable composition comprising (A) an episulfide compound containing a thiirane ring; and (B) a photo-base generator represented by the general formula (1): wherein Ar is phenyl, etc.; R is an alkyl group, etc.; —A+ is an ammonium ion; and X− is a borate anion, etc., and a coating composition comprising the photocurable composition and (C) a modified silicone oil, as well as a cured product and a coating film obtained from these compositions.
    • 提供了能够通过照射紫外线而容易地固化的光固化性组合物和光固化性组合物的固化物,以及由涂料组合物得到的涂料组合物和涂膜。 固化产物具有高的折射率,较少的变色和优异的透明度。 本发明涉及一种光固化组合物,其包含(A)含有硫杂环戊烯环的环硫化合物; 和(B)由通式(1)表示的光碱发生剂:其中Ar是苯基等; R是烷基等; -A +是铵离子; 和X-是硼酸根阴离子等,以及包含该可光固化组合物和(C)改性硅油的涂料组合物,以及由这些组合物获得的固化产物和涂膜。